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mean" values) and compared to minimally impacted reference lakes in the NCHF ecoregion (Table 2). References lakes <br />included in the last column in Table 2 include those selected to be typical of the ecoregion and minimally impacted, and <br />allow for comparison to Grass Lake. <br />Table 2. Grass Lake 2012-2013 as compared to typical range for NCHF ecoregion reference lakes' <br />Parameter Grass Lake Grass Lake Grass Lake 2-year summer <br />2012 2013 <br />mean values <br />Typical range for minimally <br />impacted lakes in NCHF <br />Number of reference lakes 43 <br />Total phosphorus(µg/L) 13.8* 12.3* 13.0* 23-50 <br />Chlorophyll mean (µg/L) 6.7 4.9 5.8 5-22 <br />Transparency (feet) <br />(meters) 1.2 1.3 1.3 1.5-3.2 <br />Total Kjeldahl Nitrogen <br />(mg/L) 0.91 0.82 0.87 < 0.60-1.2 <br />Alkalinity (mg/L) 104 107 105.7 75-150 <br />Chloride (mg/L) 35 30 33 4-10 <br />Total Suspended Solids <br />(mg/L) 2.8 2.7 2.76 2-6 <br />Total Suspended Inorganic <br />Solids (mg/L) 0.24 0.24 0.24 1-2 <br />TN:TP ratio 70:1 71:1 71:1 25:1-35:1 <br />3.9 <br />4.3 <br />4.3 <br />4.9-10.5 <br />1 Concentrations shown are the mean of samples taken May -September (i.e., summer means) <br />ug/L = micrograms per liter; mg/L = milligrams per liter <br />* One TP reading in 2012 and two in 2013 were below detectable lab limits. For the purposes of summarizing data, both non -detect samples were <br />rounded up to the lowest detectable limit for phosphorus, which is 10 ug/L. <br />Total phosphorus (TP) is often considered the nutrient that "limits" algal growth in lakes. This is because it is essential to <br />algal growth and it is typically in the shortest supply. Grass Lake's summer -mean TP is much better than the typical <br />range for NCHF lakes (Table 2), notable since it is located in such a highly developed area. For the purposes of <br />summarizing the data for Grass Lake, three non -detect samples were rounded up to the lowest detectable limit for total <br />phosphorus of 10 ug/L. The majority of the remaining samples hovered near the lowest detectable limit level, with only <br />July 2012 and 2013 readings reaching 17 and 18 ug/L, indicating that even during the hottest and driest time of the year, <br />Grass Lake's water quality is excellent2. <br />Nitrogen, while also an essential nutrient for algal growth, is typically not the "limiting nutrient" in most Minnesota <br />lakes. Total Kjeldahl nitrogen is a measure of organic nitrogen (i.e., nitrogen found in algae) and ammonia- nitrogen. <br />When combined with inorganic nitrogen, this represents total nitrogen (TN). Since inorganic nitrogen is often at or <br />below detection in lakes, we often use total Kjeldahl alone to represent TN. The ratio of TN to total phosphorus (TP) is <br />used as a simple basis for discerning which nutrient, TN or TP, is the limiting nutrient. Lakes are often considered <br />"nitrogen -limited" when the TN: TP ration falls below about 10:1. In the case of Grass Lake, its 71:1 ratio is very high, <br />over the typical range for NCHF lakes, indicating that phosphorus is the nutrient controlling algal growth in this lake. The <br />addition of phosphorus to the lake could increase the production of algae and aquatic plants. <br />2 The phosphorus detection method used by the Minnesota Department of Health changed in 2012 and 2013, and phosphorus taken up by chlorophyll -a was not <br />being included in final lab results, resulting in a low bias. The phosphorus values should be considered estimates. <br />Grass Lake (02-0113) • August 2014 Minnesota Pollution Control Agency <br />3 <br />